Blockchain has high availability because it operates 365/24/7.
Everyone who participates in the blockchain network is incentivized to keep the network alive. The incentive is, making money.
Some participants are miners.
Miners, mine to protect the network while at the same time earning money; incentive. This leads to high security. If security declines, more people mine because it becomes easier to become involved in mining. These actions enable one to have the ability to have a secure network with high availability; 365/27/7.